Palladium-Catalyzed Tethered
Intramolecular Arylation: An Unusual Synthesis of Linearly
Fused Pyridocoumarin Derivatives

K. C. Majumdar; Sanjay Nath; Buddhadeb Chattopadhyay; Biswajit Sinha

doi:10.1055/s-0030-1258246

PAPER

Palladium-Catalyzed Tethered Intramolecular Arylation: An Unusual Synthesis of Linearly Fused Pyridocoumarin Derivatives

K. C. Majumdar*, Sanjay Nath, Buddhadeb Chattopadhyay, Biswajit Sinha
Department of Chemistry, University of Kalyani, Kalyani 741235, W.B., India
e-Mail: kcm_ku@yahoo.co.in;

Abstract

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Abstract

A new synthetic protocol has been developed by the implementation of the palladium-mediated benzylic C-H activation followed by tethered intramolecular arylation strategy to give linearly fused and unusually oxidized pyridocoumarin derivatives.

Key words

oxidation - C-H activation - biaryl coupling - intramolecular cyclization - palladium acetate

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References

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